Nanosecond spectroscopy of expanding laser produced tin plasma b. We introduce a high intensity laser pulse, known as the pump. Most of the work done on libs found in the literature was based on this type of laser. Femtosecond and nanosecond laser induced breakdown spectroscopy libs were used to study trinitrotoluene tnt deposited on aluminum substrates. Timeresolved oes of nanosecond pulsed discharges in n 2 and n 2h 2o mixtures 4 4110 pulser triggered by a signal generator. Calibration analysis of bronze samples by nanosecond laser induced breakdown spectroscopy. Microscopic understanding of ultrafast dynamics in materials structure. A spectrometer based on pulsed nanosecond laser induced breakdown spectroscopy libs was employed for the quantitative determination of heavy and essential metals in salts from various sources. Introduction to femtosecond laser spectroscopy and ultrafast xray.
This paper mainly concerns on nanosecond and femtosecond laser spectroscopy of aromatic organic compounds as neurotransmitters, and plume diagnostics of the ablated species, in order to characterize the plasma dynamics, i. Pdf determination of toxic and essential metals in rock. Laserbased spectroscopic techniques have become firmly established in modern physical chemistry research because they are powerful tools for the study of. The results show that the ns laser enhanced the short. It generates a shortlived state in the sample that either can be an ion, radical or excited state. Recent advances in ultrafastlaserbased spectroscopy. Optical emission spectroscopy is used to infer the density and temperature of the. Pdf spectroscopy of laserinduced carbon plasma with. Over the detection wavelength range of 200785 nm, we have observed emission from cn and c2 molecules as the marker for the explosive with femtosecond libs. Osa enhancement of femtosecond laserinduced plasma. Tillack center for energy research, university of california san diego. Pdf calibration measurements in laserinduced breakdown. Spectroscopy of laser induced carbon plasma with nanosecond time resolution article pdf available in periodica polytechnica chemical engineering 532.
With the ns laser being imposed on the filaments, the length and the emission intensity of the filaments were largely increased. Transient absorption spectroscopy is a pumpprobe technique used to record kinetic and spectral information about shortlived states. Development of ultrashort pulse lasers for ultrafast spectroscopy. Pdf calibration analysis of bronze samples by nanosecond. The signal generator also triggers a delay generator which is used to time align the laser pulse, the iccd camera and the plasma. The rise time of the hv pulse is about 80 ns from 1090%, this is a bit larger than. Pdf dynamics of femto and nanosecond laser ablation plumes. Enhanced optical emission in laserinduced breakdown.
Nanosecond polarizationresolved laserinduced breakdown. Osa femtosecond and nanosecond laserinduced breakdown. Femtosecond laser pulses are used to modulate the thermal emission from semiconductor materials at the nanosecond timescale. Nanosecond and femtosecond laser spectroscopy of molecules. In contrast, the signal for nanosecond libs of tnt is dominated by emission from the. Nanosecond timeresolved fluorescence spectroscopy in the. The role of interpulse delay time in laser induced cu plasma with femtosecond and nanosecond doublepulse irradiation had been investigated by optical emission spectroscopy. Temporally resolved spectra of the enhanced filaments were obtained. Nanosecond polarizationresolved laser induced breakdown spectroscopy yaoming liu, john s. Nanosecond spectroscopy of expanding laserproduced tin. A visiblefrequency laser photoexcites energetic free carriers in. We demonstrate the enhancement of femtosecond fs laser induced filaments in air and nitrogen flow fields using a nanosecond ns laser.
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